www.BuyersGuideChem.com - the directory of chemicals and chemical suppliers. C-C Bond Formation (1) Photocatalysis (3) Application. orange (1) Reaction Suitability. The long lifetime of the excited state is attributed to the fact that it is triplet, whereas the ground state is a singlet state and in part due to the fact that the structure of the molecule allows for charge separation. Commission Regulation (EU) No 2015/830 of 28 May 2015. Thus, the photochemical properties of [Ru(bpy)3]2+ are reminiscent of the photosynthetic assembly, which also involves separation of an electron and a hole.[8]. Molecular Weight 958.83 . Photocatalysis (3) Application . Questions? Murillo, and M. Bochmann, in. Diphenylamine-4-sulfonic acid sodium salt, Empirical Formula (Hill Notation): C12H10NNaO3S. − radical anion as a ligand.

[Ru(bipy)3]2+ is an octahedral coordination complex. Singlet-triplet transitions are often slow. With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter. [3] Alternatively, the reducing power of [Ru(bipy)3]2+* can harnessed to reduce methylviologen, a recyclable carrier of electrons, which in turn reduces protons at a platinum catalyst. The resulting [Ru(bpy)3]3+ is a powerful oxidant and oxidizes water into O2 and protons via a catalyst. The table shows element percentages for [Ru(C 10 H 8 N 2) 3]Cl 2.6H 2 O (tris(2,2'-bipyridyl)ruthenium dichloride). Tris(triphenylphosphine) ruthenium(II) dichloride 97% Synonym: Dichlorotris(triphenylphosphine) ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride, Tris(triphenylphosphine) dichlororuthenium CAS Number 15529-49-4. [Ru(bpy)3]2+ has been examined as a photosensitizer for both the oxidation and reduction of water. For this process to be catalytic, a sacrificial reductant, such as EDTA4− or triethanolamine is provided to return the Ru(III) back to Ru(II). The following are some synonyms of tris(2,2'-bipyridyl)ruthenium dichloride: The oxidation number of ruthenium in tris(2,2'-bipyridyl)ruthenium dichloride is 2. [12], Photoredox catalysis using combination of [Ru(bpy)3]2+ catalyst and visible light is a strategy for organic synthesis. Ru(bpy)3(PF6)2, You can reference the WebElements periodic table as follows:"WebElements, https://www.webelements.com, accessed September 2020. Tris(2,2'-bipyridyl)ruthenium(II) Chloride. USA; Globally; Search term: "ruthenium bipyridine" Compare Products: Select up to 4 products. Cotton, G. Wilkinson, C.A. The following companies had been manufactured successfully in the past or were listed as Element analysis. All Rights Reserved.

Derivatives of [Ru(bpy)3]2+ are numerous. Read what you need to know about our industry portal chemeurope.com. *Please select more than one item to compare. 3 matches found for tris(2,2-bipyridine)ruthenium. ruthenium tris bipyridine, 1

Find out more about the company LUMITOS and our team. Tris(2,2-bipyridyl)ruthenium(II) chloride hexahydrate | C30H36Cl2N6O6Ru | CID 16211607 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Chemsrc provides CAS#:50525-27-4 MSDS, density, melting point, boiling point, structure, etc. For this process to be catalytic, a sacrificial reductant, such as EDTA4- or triethanolamine is provided to return the Ru(III) back to Ru(II). Melting Point (°C) 201 - 300 (4) Reaction Suitability.

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USA; Globally; Search term: "ruthenium tris bipyridine" Compare Products: Select up to 4 products. The excited state relaxes to the ground state by emission of a photon at the wavelength of 600 nm. Reproduction of any materials from the site is strictly forbidden without permission. WebElements: THE periodic table on the WWW [www.webelements.com] The family of derivatives of [Ru(bipy)3]2+ is enormous. Categories: Ruthenium compounds | Photochemistry | Coordination compounds. © 1997-2020 LUMITOS AG, All rights reserved, https://www.chemeurope.com/en/encyclopedia/Ruthenium_tris%28bipyridine%29_chloride.html, Your browser is not current. Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate According to Regulation (EC) No 1907/2006, Annex II, as amended. These complexes are widely used in biodiagnostics, photovoltaics and organic light-emitting diode. Find out how LUMITOS supports you with online marketing. © 2020  Merck KGaA, Darmstadt, Germany and/or its affiliates. Type in Product Names, Product Numbers, or CAS Numbers to see suggestions. Ruthenium-tris(2,2′-bipyridyl) dihexafluorophosphate.

The complex is chiral, with D3 symmetry. Wikipedia article "Ruthenium_tris(bipyridine)_chloride".

14323-06-9. hematology (1) histology (1) titration (1) Featured Industry.